3M GENERAL OFFICES -- 3M 77NN SUPER SPRAY ADHESIVE  -- 8040-00-782-0433
<pre>=====================  Product Identification  =====================

Product ID:3M 77NN SUPER SPRAY ADHESIVE
MSDS Date:01/01/1987
FSC:8040
NIIN:00-782-0433
=== Responsible Party ===
Company Name:3M GENERAL OFFICES
Address:3M CENTER
City:SAINT PAUL
State:MN
ZIP:55144-1000
Country:US
Info Phone Num:612-733-1110
Emergency Phone Num:612-733-1110
CAGE:04963
=== Contractor Identification ===
Company Name:3M MINNESOTA MINING AND MFG CO ADHESIVES SEALERS DIV
Address:3M CTR
Box:City:SAINT PAUL
State:MN
ZIP:55144-1000
Country:US
Phone:800-364-3577/651-737-6501(24 HOURS)
CAGE:04963

=============  Composition/Information on Ingredients  =============

Ingred Name:METHYLENE CHLORIDE	(SARA III)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 14.0%
OSHA PEL:500 PPM/C,1000; Z2
ACGIH TLV:50 PPM, A2; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:CHLORODIFLUOROMETHANE
CAS:75-45-6
RTECS #:PA6390000
Fraction by Wt: 32.0%
OSHA PEL:1000 PPM
ACGIH TLV:1000PPM; 9192
Ozone Depleting Chemical:2

Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE)  (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 14.0%
OSHA PEL:350 PPM/450 STEL
ACGIH TLV:350 PPM/450STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1

Ingred Name:1,4-DIOXANE (DIETHYLENE DIOXIDE)  (SARA III)
CAS:123-91-1
RTECS #:JG8225000
OSHA PEL:S, 100 PPM
ACGIH TLV:S, 25 PPM; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:STYRENE-BUTADIENE RUBER, TERPENE & ROSIN ESTER RESINS,
    ANITOXIDANTS; CAS 9003-55-B
CAS:9003-55-8
RTECS #:WL6478000
Fraction by Wt: 11.0%

=====================  Hazards Identification  =====================

Effects of Overexposure:EYE:IRRIT.SKN:DEFAT W/IRRIT
    POSS.INHL:IRRIT,DIZZ,HEADACHE,NAUSEA.INGEST:UNLIKELY FROM AEROSOL
    CAN

=======================  First Aid Measures  =======================

First Aid:EYE:FLUSH W/COPIOUS WATER 10 MIN,CALL PHYS. SKN:WASH W/SOAP &
    WATER. INH:REMOVE TO FRESH AIR. INGEST: CALL PHYSICIAN.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:NON-FLAMMABLE
Fire Fighting Procedures:USE SCBA WITH FIRES INVOLVING THIS MATERIAL.
Unusual Fire/Explosion Hazard:AEROSOL CANS MAY EXPLODE WHEN HEATED.

==================  Accidental Release Measures  ==================

Spill Release Procedures:COLLECT SPILLAGE W/ABSORBENT MATL & STORE IN
    SEALED METAL CONTAINER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE CANNISTERS AT TEMP 12T TO EXCEED
    120F. AVOID HIGH TEMP AND OPEN FLAMES, WELDING ARCS.
Other Precautions:USE AEROSOL ONLY IN PROPERLY VENTILATED AREAS. AVOID
    OVERSPRAYING & PRLONGED INH VAPORS. AVOID CONTACT EYE/SKN.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NONE SPECIFIED BY MFR.
Ventilation:LOC/MECH TO PREVENT VAPOR BUILDUP ABOVE ESTABLISHED TLV'S.
Protective Gloves:APPROVED GLOVES
Eye Protection:SAFETY GLASSES
Other Protective Equipment:NONE
Supplemental Safety and Health
UPDATE PER 3M MSDS (OSHA)DTD 8NOV85,DOC#1033075. 3M
    ID#62-4494-4830-7.FORMER PN/:SCOTCHORIP SPRAY ADHESIVE 77N.

==================  Physical/Chemical Properties  ==================

HCC:V2
Vapor Density:>4
Spec Gravity:1.3
Evaporation Rate &amp; Reference:<1 (ETHER=1)
Solubility in Water:VERY LOW
Appearance and Odor:CLEAR, LIGHT AMBER, SWEET ODOR
Percent Volatiles by Volume:89

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:AEROSOL CAN - AVOID EXPOSURE TO TEMP ABOVE
    120F/49C.
Hazardous Decomposition Products:HCL VAPORS, OTHER HAZARDOUS
    CHLORINATED COMBUSTION PRODUCTS

====================  Disposal Considerations  ====================

Waste Disposal Methods:EMPTY CANNISTERS DISPOSABLE IN APPD LANDFILL.
    INCINERATE EMPTY CANS, RUPTURED CANS, AND ABSORBANT ONLY IN
    PERMITTED FACILITY APPROVED FOR AEROSOL CANS. DO NOT ATTEMPT INCIN
    IN HOUSEHOLD INCINERATOR. E PA HAZ WASTE D001 (IGNITABLE).CONTAINS
    HALOGENS.

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